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Beilstein J. Org. Chem. 2015, 11, 2334–2342, doi:10.3762/bjoc.11.254
Graphical Abstract
Figure 1: Three new bromotyrosine derivatives isolated from sponge Aplysina lacunosa: 14-debromo-11-deoxyfist...
Figure 2: Bromotyrosine alkaloids and brominated compounds isolated from the sponge Aplysina lacunosa.
Figure 3: 1,1-ADEQUATE spectrum of 14-debromo-11-deoxyfistularin-3 (1).
Figure 4: The tissue damage induced chemical conversion from fistularin-3 (5) to 19 by an undefined enzyme in...
Figure 5: Diacetylhexadellin B (20) isolated from sponge Hexadella sp.
Figure 6: Bromotyrosine alkaloid (21) isolated from the sponge Verongula sp.
Beilstein J. Org. Chem. 2014, 10, 613–621, doi:10.3762/bjoc.10.52
Figure 1: Structures of the new compounds siphonodictyals E1–E4 (1–4) and cyclosiphonodictyol A (5) isolated ...
Figure 2: Structures of the related known compounds siphonodictyal B1 (6), siphonodictyal B2 (7), siphonodict...
Figure 3: Selected 1H,13C-HMBC correlations (H → C) and 1H,1H-COSY correlation (bold line) observed for sipho...
Figure 4: Selected 1H,13C-HMBC correlations (H → C) observed for siphonodictyal E2 (2).
Figure 5: Possible constitutions for the aromatic moieties of siphonodictyals E2 (2) and E3 (3) (sum over all...
Figure 6: Selected 1H,13C-HMBC correlations (H → C) observed for siphonodictyal E4 (4a).
Figure 7: Proposed biogenesis of 4a starting from the hypothetical precursor 3-ox with an acyclic sesquiterpe...
Figure 8: Hypothetical biogenesis of the bicyclic sesquiterpenoid moiety from the acyclic precursor of the si...